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The zinc-nickel alloy electroplating process is an important metal
surface treatment technology that can form a zinc-nickel alloy
coating on the metal surface to improve the corrosion resistance,
hardness and aesthetics of the metal.
The basic principle of zinc-nickel alloy electroplating
Zinc-nickel alloy electroplating is a process of depositing a layer
of zinc-nickel alloy on the metal surface using the principle of
electrolysis. The electroplating solution contains zinc ions and
nickel ions. When the power is turned on, the cations discharge on
the cathode (i.e. the metal to be plated) to form a zinc-nickel
alloy coating. This alloy coating combines the excellent properties
of zinc and nickel, such as the sacrificial anode protection of
zinc and the corrosion resistance of nickel.
Electroplated zinc-nickel alloy is divided into high nickel and low
nickel
1. High nickel generally has a nickel content of 12-15%. Due to the
need for trivalent chromium passivation, nickel can also reach
12-18%
Generally, this is a requirement, especially in the automotive
industry, which is basically in this range.
2. The nickel content of low-nickel zinc-nickel alloy coating is
5-10%, which is relatively small. Generally, zinc-nickel alloy
coating with low nickel content has good corrosion resistance and
good ductility, so it will be used in some workpieces that need to
be pressed or drawn after electroplating.
3. What kind of zinc-nickel alloy process is suitable for roller
zinc-nickel alloy electroplating process?
There are two types: alkaline and acidic. The alkaline zinc-nickel
alloy electroplating process has good stability and excellent
coating quality. Most electroplating companies now use alkaline
process.
When alkaline zinc-nickel alloy electroplating is applied to roller
plating, the process characteristics should be required
According to the characteristics of roller plating:
1. The process has good deep plating ability. It is understood that
the process deep plating ability provided by most additive
suppliers with a nickel content of more than 10% on the market is
suitable for roller plating requirements.
2. The current efficiency is high and good. The alkaline
zinc-nickel alloy coating will dissolve under alkaline conditions.
If the current efficiency is too low, especially in the low current
zone, the coating may not be plated. The characteristics of the
barrel plating itself determine that the coating is slow to plate
and takes a long time to dissolve. If the current efficiency is too
low, it takes more patience to plate a tank. At present, many
alkaline zinc-nickel alloy electroplating processes on the market
have an efficiency of about 35%. It is normal to take 4-5 hours to
plate 8 microns thick. There are also high-efficiency alkaline
zinc-nickel alloy processes on the market with an efficiency of
about 75%, which can save more than half of the time.
3. For the alkaline zinc-nickel alloy process, the electroplating
temperature is required to be below 35 degrees, so refrigeration
equipment is required.
4. Additive selection. At present, many companies on the market
need to add 5 or 6 additives at the same time when electroplating
zinc-nickel alloy processes, which brings great inconvenience to
the initial users, addition and maintenance. The fewer the types of
additives, the clearer the functions of various additives, the
better. What is the difference between the black zinc-nickel alloy
and the transparent zinc-nickel alloy? Is the zinc-nickel alloy
black and transparent after electroplating, or is it directly
electroplated black? If it is the former, the change is that the
passivation agent has nothing to do with the alloy. If it is the
latter, there should be a black light agent in the additives during
electroplating, otherwise the electroplated color should be
silver-white.
Process flow of zinc-nickel alloy electroplating
1. Pre-plating treatment: including degreasing, rust removal, activation and other steps to ensure that the metal surface is clean and has good conductivity.
2. Electroplating process: The metal to be plated is immersed in the electroplating solution as the cathode and electroplated by electricity. The zinc ions and nickel ions in the electroplating solution are discharged on the cathode to form a zinc-nickel alloy coating.
3. Post-plating treatment: including cleaning, drying, passivation and other steps to protect the coating and improve its performance.
Key points of zinc-nickel alloy electroplating
1. Preparation of electroplating solution: The concentration of
zinc ions and nickel ions in the electroplating solution needs to
be precisely controlled to ensure that the ratio of zinc and nickel
in the coating is appropriate. At the same time, an appropriate
amount of additives must be added to the electroplating solution to
improve the performance and appearance of the coating.
2. Control of electroplating conditions: Parameters such as current
density, electroplating time and electroplating temperature have an
important influence on the quality of the coating. It needs to be
adjusted according to the actual situation to obtain the best
electroplating effect.
3. Post-treatment process: The post-treatment process is crucial to
protect the coating and improve its performance. The cleaning
process needs to be thorough to avoid corrosion of the coating by
residual electroplating solution; the drying process needs to
control the temperature and time to prevent cracking or
discoloration of the coating; passivation treatment can enhance the
corrosion resistance of the coating.
In short, the zinc-nickel alloy electroplating process is an important metal surface treatment technology. By precisely controlling the preparation of the electroplating solution, the electroplating conditions and the post-treatment process, a zinc-nickel alloy coating with excellent performance can be formed on the metal surface.